I found a really old thread where someone else did this exact thing and was selling it! Very unlikely to still have it now, and they haven't been around since they posted it (back in 2016) but you can at least see an example of their HUGE car-sized cauldron looking at the pics:
Used as a prop for last year's marching band show. Looking for best offer. Come and pick it up. We're located in Columbus, Indiana. Phone 812-322-9212 Photos attached.
www.halloweenforum.com
For a 6 foot prop, I'd likely not want to use paper mache just because it would be sooooo very very time consuming and unlikely to dry for weeks if you got the layers thick enough to withstand moving.
Does it have to be seen from all sides (so fully round) or would the seating be just in the front so it could it be a large cut out flat piece with lighting/fogger behind it? Because you could easily cut out a LARGE piece of foamcore (4 foot x 8 foot sheets available in places like Home Depot or Lowes) and painted (just don't use spray paints as they melt foam/styro). Glue down to lightweight plywood structure for more stability and able to rig up a folding footing/stand on the backside.
But if you are really wanting a fully rounded version... maybe pick up a couple of baby plastic wading pools and use one as the top/mouth of the cauldron (paint black obviously and it would be the perfect depth to hold a fogger/lights and also easy access), one as a base with some 1x1 or 2x2 wood posts attaching them together at top/bottom creating a cylinder base for the rounded structure, then create the rounded side ribs from cardboard (fridge/appliance boxes - ask at home improvement stores and might be able to score for free) and then skin the whole thing with black plastic table cloths (check out your local dollar store, but thicker would be better so maybe black landscaping fabric?). I'm picturing a lightweight structure, but should be pretty stable I would think. I'm basing the general build off a smaller version in this tutorial:
So here is a project inspired (copied from) by SKAustin. It is essentially a large rope handled bin with the rope removed. I then needed to make a bunch of ribs to create the cauldron shape. Taking the time to make a great template was key! I then acquired some heavy duty / thick cardboard...
www.halloweenforum.com
I'd have a way to get to the inside or glue something on the inside bottom area that gives it a little bit of weight so it doesn't fall over/shift if the weather is windy, but you also could cut out a smaller diameter section from the top baby pool and have a REALLY deep cauldron for reals and just need a step ladder to drop things into it and remove them when it's ready to be put up.