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PVA glue + paint = Goo?

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I thought I'd be smart and mix glue and paint so I could do some glue-mache quicker. Have you ever seen chocolate seize? That's what this did. It became grainy, gloppy, and thick. On par with instant pudding, but clumpy.

So I used some on an area that's easy to clean off if it refuses to dry. And it dried fine, pretty interesting actually.

Is this a thing all paint does? I have this as an unmarked OOPS can and it smells like latex paint (it's only marked Interior Eggshell).
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